The presence of the Etendeka flood basalts in northwestern Namibia is taken as evidence for the activity of the Tristan da Cunha mantle plume during the breakup process between Africa and South America. We investigate seismic anisotropy beneath NW Namibia by splitting analysis of core-refracted teleseismic shear waves (XKS phases) to probe mantle flow and lithospheric deformation related to the tectonic history of the region. The waveform data were obtained from 34 onshore stations and 12 Ocean Bottom Seismometers. The results presented here are from joint splitting analysis of multiple XKS phases. The majority of the fast polarization directions (FPDs) exhibit an NE-SW orientation consistent with a model of large-scale mantle flow due to the NE motion of the African plate. No evidence for a direct effect of the mantle plume is observed. In the northern part, we observe NNW-SSE-oriented FPDs that is likely caused by shallow lithospheric structures.