Entry
|
Catalyst
|
Conv.
(%)
|
Yield 2aa
(%)
|
Yield 3aa
(%)
|
Yield 4aa
(%)
|
1 |
Cu(OTf)2
|
< 5 |
trace |
ND |
ND |
2 |
Ni(cod)2
|
< 5 |
ND |
ND |
ND |
3 |
Ni(acac)2
|
< 5 |
ND |
ND |
ND |
4 |
Ti(OiPr)4
|
10 |
trace |
ND |
ND |
5 |
Rh(cod)(acac) |
10 |
trace |
trace |
trace |
6 |
CoBr2/bpy |
< 5 |
trace |
ND |
ND |
7
|
CoF2/
tBuXantphos
|
< 5
|
trace
|
ND
|
ND
|
8 |
L1-FeCl2 |
> 95 |
88(69) |
trace |
trace |
9 |
L2-FeCl2 |
> 95 |
93 |
trace |
trace |
10 |
L3-FeCl2 |
> 95 |
93(91) |
trace |
trace |
11 |
L4-FeCl2 |
> 95 |
90 |
trace |
trace |
12 |
L5-FeCl2 |
> 95 |
94 |
trace |
trace |
13 |
L6-FeCl2 |
> 95 |
82(76) |
5 |
6 |
14 |
L7-FeCl2 |
91 |
56 |
5 |
6 |
15 |
L8-FeCl2 |
38 |
24 |
trace |
trace |
16b
|
L9-FeCl2 |
> 95 |
22 |
trace |
trace |
17 |
L10-FeCl2 |
67 |
35 |
trace |
trace |
18 |
FeCl2
|
< 5 |
trace |
ND |
ND |
19 |
L3 |
< 5 |
trace |
ND |
ND |